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2
MATERIALSANDMETHODS
2.1
MainSourcesofBOW
BOW are process effluents that occur in the engine
room,incargoholds,aswellasduringtheoperation
ofthedeckanddeckmachineryundertheconditions
oftheshipʹsoperation.
According totheanalysisfulfilledforsea vessels
(bulkers,tankers,RO‐ROtypevessels,
etc.)operation,
it was found that the main generators of the
components that form the basis of the BOW, which
finallyendupinbilgewellsandtanks,are:condensed
liquids from cooling systems of main and auxiliary
engines; condensed liquids from starting and
auxiliary compressors for compressed air supply;
liquids condensated from the deck heater system;
distillate from refrigeration units and compressor
units servicing air conditioning systems; liquids
condensated from for oil tanks (separator tank,
incinerator tank, etc.) heating systems; leaks in
pipelines and ship auxiliary mechanisms, in
particular: sea water, fuel, oilandsteamsystems (in
most cases, such
leaks are typical for ships whose
constructionandoperationperiodexceedstenyears);
waste water with light chemical products after
cleaning or scrubbing the decks of the engine room
andpalletsofshipauxiliarymechanisms;productsof
washing or scouring of: decks, deck machinery,
processequipmentandauxiliaryequipment;running
water forpersonalhygiene of workersin the engine
room of large multi‐tonnage vessels; drainage of
rainwater from ship chimneys at the absence of
separatedischargelines;cargohold ortankwashing
productscollectedinaseparate,so‐calledSLOPtank;
products of oil spills during bunkering or during
loading
and unloading operations, collected in a
separate SLOP tank; drains from bow, stern and
centralshipwellsandgaters.
During operation of water transport facilities
quantitativechangesinthetotalvolumesofgenerated
BOW are determined by a combination of the
followingreasons:theoperationalintensityoftheship
power
plant; total power and number of auxiliary
boiler equipment; non‐uniform loading of the shipʹs
holds with the same type of cargo; the quality of
inspectionandrepairoftanksandfuelandoilsupply
systems,etc.
2.2
SpecificFeaturesofBOW
ThequalitativeandquantitativecompositionofBOW
isnotuniversalandineachcaseisavariablevalue.It
directly depends and is determined by the ship
technologicalprocessesthat generateit. Theaverage
statisticallistofthemainBOWcomponentsincludes:
dissolved gases; oils (industrial, used
machine oils,
etc.)withaconcentrationofupto1000mg/l;wasteoil
productsandtheircomponents,aswellasoilsludge
(concentration up to 8000 mg/l); detergents
(concentration up to 5‐10 mg/l); suspensions
(concentration up to 300‐500 mg/l); sulfates
(concentrationupto200mg/l);phenols(concentration
up
to50mg/l).
Alloftheabovecomponents,exceptforgases,are
characterizedbyalargespecificgravitycomparedto
thesameparameterforwater, whichis thebasis for
thefurtherprocessfortheirseparationfromtheBOW
flow.
IfweclassifyBOWcomponentsasgaseous,liquid
and solid we
can state that, depending on the ratio
between the densities of the separately considered
componentρc and waterρw, the following two
optionsforthebehaviorofthemixturearepossible:
in a stationary state, over time atρc<ρw, for a
certaintimeduring stratification,the components
oftheBOWwillfloatup;
inmotionwithabsenceofliftingforcesandρc>ρw,
thecomponentsoftheBOWwillprecipitate.
ConsideringBOWasamulticomponentflowbeing
processeditisworthtonote,thatwhenanalyzingthe
operation practice of separators, it was found that
high purification efficiency occurs ata concentration
of harmful
components only up to 100 mg/l [3, 19].
Exceeding this value leads to the complication of
methodsusedfortheirseparation.
2.3
BOWSeparationMethods
The general principles of technological schemes
functioningintendedforBOWseparationaredirectly
determined by the work processes used to separate
their constituent components. Three main directions
of water purification in the vessel operating
conditionscanbedistinguishedprincipally:physical,
chemicalandbiological.Inmostcases,theyare
used
incombinationwitheachother[1,3,11,13,16].
The basis of the physical direction is the use of
mass and less often surface forces. In this case, the
mass forces include the forces of inertia, gravity,
floating,etc.
The implementation of chemical processes in the
BOW separation
is based on the use of various
reagents in combination with electrochemical
oxidationoftheprocessedflow[2,12].
ThebiologicaldirectionofBOWseparationimplies
theuseofmicroorganismsthatensurethedestruction
of the constituent components of petrochemical
productsduringthetimeoftheirlifeactivity[20,25].
During
research,ageneralstructuralclassification
of existing methods for the BOW separation was
developed (Fig. 1). It was done in the form of a
diagram, which shows that all ship technological
schemes for BOW processing are based on twelve
differenttechnologies.
The analysis of their performance indicators has
shown that
during the vessel’soperation,separators
which operate on the principle of centrifugal flow
separation are most widely used. The main
disadvantageofmarinecentrifugalseparatorsistheir
limitedcapacity,i.e.inabilitytoprocesslargevolumes
of BOW in short periods of time. Basically, such a
limitation is caused by the length
of the path that
particlesofoilyimpuritieshavetopassbybeforethey
hit the free surface of water or stick to the contact
surfaceoftheseparator.
During separation of BOW, pre‐filtration of the
processedmultiphaseflowisusedalways.Itisbased
on the physical cleaning
method and is founded on